Journal of Liaoning Petrochemical University
  Journals
  Publication Years
  Keywords
Search within results Open Search
Please wait a minute...
For Selected: Toggle Thumbnails
Theoretical Study on Raman Spectra of Janus MoSSe Single⁃Layer under Bi⁃Axial Strain
Wei SUN, Hongzhi SUN, Bo ZHAO, Huaihong GUO
Abstract500)   HTML5)    PDF (3619KB)(68)      

Monolayer Janus transition metal disulfides have low dimension, high mobility, and peculiar electronic structure properties, which have potential applications in electronics and optoelectronic devices. In devices made of monolayer Janus transition metal disulfide and substrate materials,are usually stressed due to lattice mismatch between monolayer Janus transition metal disulfides and substrate, it is significant to study the strain effect on physical properties of monolayer Janus transition metal disulfides through Raman scattering.This paper systematically investigate the biaxial strain effect on the atomic structure, electronic structure and Raman spectra of monolayer Janus MoSSe. The results show that monolayer Janus MoSSe can exhibit a band gap transition from direct to indirect one under biaxial strain, due to both the energy shift of bonding orbitals between the top of the valence band and the bottom of the conduction band and the sensitivity to strain. This paper also thoroughly study the strain effect on the Raman shift and intensity of monolayer Janus MoSSe. It is found that under biaxial strain modulation from decreasing compressive to increasing tensile, for the Raman shift, the three peaks of E1, E2, and A 1 1 red?shift, while the peak of A 1 2 blue?shifts abnormally with decreasing compressive strain; for the intensity, the peak intensity of the doubly?degenerate modes (E1,E2) increases monotonically, while singly?degenerate modes shows the opposite trend, except for the A 1 1 which intensity decreases with decreasing compressive strain and then increases with tensile strain. This paper propose a simple model to comprehend the strain effect. This theoretical study may supply an effective means to quickly and quantitatively characterize the strain size and type in Janus materials through the frequency difference and intensity ratio between typical Raman peaks.

2024, 44 (1): 35-42. DOI: 10.12422/j.issn.1672-6952.2024.01.006
Study on the Method of Tapping Potential in Later Stage of Large Displacement Production in Marine Strong Bottom Water Sandstone Reservoir
Changwei Sun, Jia Cheng, Renkai Jiang, Yue Gu, Xiaodong Li
Abstract214)   HTML2)    PDF (1896KB)(145)      

In view of the large displacement production of marine sandstone FOURD reservoir, it is found that the water drive pore volume multiples at different locations are different during the development process of bottom water reservoir, while the experiments measured in the conventional industry standard are insufficient to express the seepage characteristics of the reservoir after the high flooding multiple. The high?power water drive experiment shows that the half logarithm of core displacement multiples with different clay content has a linear relationship with oil displacement efficiency, and the water drive sweep volume of bottom water reservoir increased slowly. Based on the actual data of FOURD reservoir, the time?varying characteristics of the reservoir were characterized and studied by numerical simulation technology. According to the different north?south dynamics of FOURD reservoir, the water flooding degree in the south area is high and the sweep degree is difficult to improve. The oil displacement efficiency of the reservoir is improved by liquid extraction, and in the north area and where the impact degree is not high, the later potential tapping mode of well network encryption is adopted. After adopting the limit tapping potential strategy described in this paper, according to the results of numerical simulation and practical mine application, the swept volume increased by 11.1%, and the calibration recovery increased by 4.5%.

2022, 42 (6): 44-48. DOI: 10.3969/j.issn.1672-6952.2022.06.007
Theoretical Study on Double Resonant Raman Scattering in Janus MoSSe Monolayer
Hongzhi Sun, Wei Sun, Bo Zhao, Huaihong Guo
Abstract394)   HTML    PDF (1666KB)(214)      

The double resonance Raman (DRR) peaks of Janus MoSSe monolayer are important fingerprints of material characteristics. However, the origin of DRR peaks is still poorly understood and needs urgent clarification. Based on density functional theory, high?order quantum perturbation theory and group theory analysis, the DRR spectra of Janus MoSSe monolayer were studied theoretically and systematically. It is found that the inverse lattice wave vector of the electro?optical resonance coupling process of Janus MoSSe monolayer depends on the laser energy, and any wave vector may appear in the first Brillouin zone. Based on group theory analysis, the symmetry conditions for the generation of DRR activity were deduced, and the fundamental reason for the occurrence of a large number of DRR peaks in the Janus structural system was elucidated. This study provides theoretical guidance for understanding the DRR processes occurring in two?dimensional Janus structural system, and provides a rational theoretical means for clarifying the origin of the DRR peaks.

2022, 42 (3): 30-36. DOI: 10.3969/j.issn.1672-6952.2022.03.006